Rate of reaction

O Level / IGCSE Chemistry · Chemical reactions. A short explanation of the idea, the rules to remember, the mistake to avoid, a worked example and practice questions with answers.

Test this topic freeAll O Level / IGCSE Chemistry topics

The idea

The rate of reaction is how fast reactants are used up or products are formed. It can be followed by measuring the volume of gas collected, or the loss in mass as a gas escapes, at regular times.

Collision theory explains rate. Particles react only when they collide with at least the activation energy. Anything that makes these successful collisions happen more often makes the reaction faster.

On a graph of volume or mass against time, a steeper line means a faster reaction. The line is steepest at the start, when the reactants are most concentrated, and becomes flat when one reactant is used up.

Rules to remember

Common mistake

Students say a faster reaction makes more product. If the amounts of reactants are the same, the graph is steeper but levels off at the same height.

Worked example

Magnesium reacts with dilute acid. The volume of hydrogen collected is 48 cm3 after 20 s and 72 cm3 after 60 s. Compare the average rate in the first 20 s with the average rate from 20 s to 60 s.

  1. First 20 s: rate = 48 ÷ 20 = 2.4 cm3/s.
  2. From 20 s to 60 s: volume made = 72 − 48 = 24 cm3 in 40 s.
  3. Rate = 24 ÷ 40 = 0.6 cm3/s.

Answer: 2.4 cm3/s at first, then 0.6 cm3/s. The reaction slows down because the acid becomes less concentrated, so collisions are less frequent.

Practice questions

Try each one, then open the answer.

1. A reaction takes 80 s to finish at 20 °C. The rate of this reaction doubles for every 10 °C rise in temperature. About how long will it take at 40 °C?

  1. A
    10 s
  2. B
    20 s
  3. C
    40 s
  4. D
    160 s
Show answer

Answer: B. A 20 °C rise is two steps of 10 °C, so the rate doubles twice and becomes four times faster. The time is therefore 80 ÷ 4 = 20 s.

2. What is a catalyst?

  1. A
    a substance that slows down a reaction and is used up in doing so
  2. B
    a substance that is used up during a reaction and speeds it up
  3. C
    a substance that speeds up a reaction and is unchanged at the end
  4. D
    a substance that raises the yield by shifting the equilibrium position
Show answer

Answer: C. A catalyst speeds up a reaction by providing a route with a lower activation energy and is chemically unchanged at the end.

3. Powdered calcium carbonate reacts faster with acid than lumps of the same mass. Why?

  1. A
    the powder is a different, more reactive form of the compound
  2. B
    the powder is more concentrated, so its particles collide more often
  3. C
    the powder has a lower activation energy than the lumps do
  4. D
    the larger surface area exposes more particles, so collisions are more frequent
Show answer

Answer: D. A larger surface area exposes more particles to the acid, increasing the frequency of successful collisions.

More questions on this topic

Keep going

← Physical and chemical changesReversible reactions and equilibrium →All rules on one pageStuck? Ask a question