Magnesium reacts with dilute acid. The volume of hydrogen collected is 48 cm3 after 20 s and 72 cm3 after 60 s. Compare the average rate in the first 20 s with the average rate from 20 s to 60 s.
- First 20 s: rate = 48 ÷ 20 = 2.4 cm3/s.
- From 20 s to 60 s: volume made = 72 − 48 = 24 cm3 in 40 s.
- Rate = 24 ÷ 40 = 0.6 cm3/s.
Answer: 2.4 cm3/s at first, then 0.6 cm3/s. The reaction slows down because the acid becomes less concentrated, so collisions are less frequent.